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تری کلرواستونیتریل 25 گرمی کد A10565 ساخت شرکت آلفاایسر آلمان
| CAS: | 545-06-2 | MDL: | MFCD00001842 | EINECS: | 208-885-7 | ||
|---|---|---|---|---|---|---|---|
| UN#: | UN3276 | Hazard Class: | 6.1 | Packing Group: | III |
Due to government transport regulations, this item cannot be shipped to your country.
Chemical Properties
| Formula: | C2Cl3N | Boiling point: | 85-86° | |
|---|---|---|---|---|
| Formula weight: | 144.39 | Density: | 1.44 | |
| Melting point: | -44° | Refractive Index: | 1.4410 |
Literature References
The combination with PPh3 is superior to the popular CCl4-PPh3 system for conversion of carboxylic acids to acyl chlorides: Tetrahedron Lett., 40, 5323 (1999). It also converts allylic alcohols to the corresponding chlorides: Russ. J. Org. Chem., 31, 1019 (1995).
In the presence of a base, e.g DBU, reacts with alcohols to form trichloroacetimidates, which are a useful means of protection, readily cleaved by TsOH/MeOH, DBU/MeOH or Zn/NH4Cl: Synlett, 753(1999). These imidates are activated towards displacement by nucleophiles. Glycosyl imidates, formed in the presence of a base such as K2CO3 or DBU, are widely applied as glycosyl donors in oligosaccharide synthesis. Reaction with the free OH of the glycosyl acceptor occurs under mild conditions, promoted by a Lewis acid, e.g. BF3 etherate or TMS-OTf, to form, respectively, either the ß- or ɑ-glycoside as the major product: Angew. Chem. Int. Ed., 25, 212 (1986). For reviews, see: Chem. Rev., 93, 1503 (1993); Adv. Carbohydr. Chem. Biochem., 50, 21 (1994); Contemp. Org. Synth., 3, 173 (1996). The imidates of allylic alcohols, prepared using NaH, or, more conveniently, KOH under phase-transfer conditions: Tetrahedron Lett., 37, 1481 (1996), undergo a [3,3]-sigmatropic rearrangement to derivatives of allylamines: J. Am. Chem. Soc., 96, 597 (1974); 98, 2901 (1976). For an example, see: Org. Synth. Coll., 6, 507 (1988). Review: Acc. Chem. Res., 13, 218 (1980):
Aromatic aldoximes are dehydrated to nitriles by a similar cyclic mechanism: J. Org. Chem., 38, 2241 (1973).
Reacts with hydrogen peroxide, to give, in situ, peroxytrichloroacetamidic acid, a reagent for the epoxidation of alkenes under essentially neutral conditions: J. Org. Chem., 48, 888 (1983).
For a review of the chemistry of trichloroacetonitrile, see: Heterocycles, 43, 1083 (1996).
Other References
| Merck: | 14,9628 |
|---|---|
| Beilstein: | 605572 |
| UN#: | UN3276 |
| Harmonized Tariff Code: | 2926.90 |
GHS Hazard and Precautionary Statements
Hazard
Statements
:
H301-H311-H331-H411
Toxic if swallowed. Toxic in contact with skin. Toxic if inhaled. Toxic to aquatic life with long lasting effects.
Toxic if swallowed. Toxic in contact with skin. Toxic if inhaled. Toxic to aquatic life with long lasting effects.
Precautionary
Statements
:
P261-P301+P310-P361-P302+P352-P405-P501A
Avoid breathing dust/fume/gas/mist/vapours/spray. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. Remove/Take off immediately all contaminated clothing. IF ON SKIN: Wash with plenty of soap and water. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.
Avoid breathing dust/fume/gas/mist/vapours/spray. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. Remove/Take off immediately all contaminated clothing. IF ON SKIN: Wash with plenty of soap and water. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.
Risk & Safety
| Risk Phrases: | 23/24/25-51/53 |
|---|---|
| Toxic by inhalation, in contact with skin and if swallowed. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. | |
| Safety Phrases: | 45-61 |
| In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Avoid release to the environment. Refer to special instructions/Safety data sheets | |
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| TSCA: | Yes |
| RTECS: | AM2450000 |
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